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HADING AND HIGHLIGHTING, METHOD #3

Step 1: Color your flats, but instead of filling them with mid-tones fill them with the color you want the darkest shadows to be.

I find it can also help to have a dark color in the background as well.
Step 2: Decide where your light source is. This technique works well on more realistic anatomy and/or unusual light sources, so I'm going to pretend that for some reason the subjects hand is glowing and that's where the light for the picture is coming from.
Step 3: Now choose an area to start with and pick a color between your shadow color and what you want to be the lightest color. My shadow color is a dull purplish red and my lightest color is gonna be a bright yellow, so my initial highlight color is a peach. Imagine where the light from your light source would hit your subject and put the color there.
Step 4: Continue using colors closer to your highlight color until the section is fully highlighted
Step 5: Do the same thing to the rest of the sections.
Step 6: This coloring method doesn't just work for unusual light sources. It can be used for a generic light source as well.
Flats
Skin highlight color 1
Skin highlight color 2
Skin highlight color 3
Whole image highlighted

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